Low Self-Discharge, High-Voltage Supercapacitors Using Porous Carbon
Supercapacitors rely mostly on double-layer capacitance to bridge the divide between chemical batteries and traditional capacitors, but they come with a number of weaknesses. Paramount among these are their relatively low voltage of around 2.7 V before their electrolyte begins to decompose, as well as their relatively high rates of self-discharge. Here a new design using lignin-derived porous carbon electrodes and a fluorinated diluent was demonstrated by [Shichao Zhang] et al., as published in Carbon Research , that seems to address these issues. Most notable are the relatively high voltage of 4 V, an energy density of 77 Wh/kg and a self-discharge rate that’s much slower than that of conventional supercapacitors. In comparison with these supercapacitors, these demonstrated versions are also superior in terms of recharge cycles with 90% of capacity remaining after 10,000 cycles, which together with their much higher energy density should prove to be quite useful. This feat is acc...